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Preheat the oven to 350. Spray 3 (8-inch) round cake pans with cooking spray. Line the bottoms of the pans with parchment paper, spray the paper with more cooking spray, and set pans aside.
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Combine the sugar, butter, and oil in a large mixing bowl and whisk until combined. Beat in the eggs and vanilla.
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Combine the flour, baking powder, baking soda, salt, and cocoa powder in a medium mixing bowl and whisk to combine.
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Whisk half of the dry ingredients into the wet ingredients, then slowly mix in half of the coffee until just incorporated.
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Stir in the remaining dry ingredients, then the remaining coffee. Stir until well combined and free of lumps.
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Divide batter evenly between the prepared pans and bake for 28 to 32 minutes, until the cakes spring back when touched gently with your fingertip. Let cake layers cool in pans for 15 minutes, then carefully remove from the pans to cool completely on a wire rack.