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Preheat the oven to 350 degrees. Generously spray a 12-cup Bundt pan with cooking spray (don’t forget to spray the inner tube). Set pan aside.
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Combine the cake mix, pudding mix, eggs, and oil in a large mixing bowl. Beat with an electric mixer until smooth.
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Add the coffee, sugar, Kahlua, and vodka, and mix well. The batter will be thin.
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Pour into prepared pan and smooth the top with a spatula. Bake for 45 to 55 minutes, until a toothpick inserted into the center of the cake comes out clean.
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Cool in the pan for 10 minutes, then carefully invert cake onto a serving platter and make the glaze.