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Preheat the oven to 350 degrees. Spray a 13- by 9-inch baking pan with cooking spray and lightly dust with flour. Set pan aside.
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Combine the cake mix, eggs, vegetable oil, room temperature water, lemon zest, and 1/2 cup lemonade concentrate in a large mixing bowl. Beat with an electric mixer set to medium for 2 minutes. Pour into prepared pan. Bake as the box directs for a 13- by 9-inch cake.
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Remove cake from the oven and allow to cool for 20 minutes. While cake is cooling, stir the gelatin into the boiling water; continue stirring until it dissolves, about 2 minutes. Stir in the the remaining 2 tablespoons of lemonade concentrate.
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Use the handle of a wooden spoon to poke holes 1 inch apart across the whole cake. Pour the jello mixture over the cake, then cool completely.
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Once cake is cool, stir the lemon zest into the whipped topping. Spread into an even layer over the cake, then cover loosely with plastic wrap and refrigerate for at least 2 hours (or overnight). Garnish with sliced berries and serve.