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Preheat the oven to 350. Spray 3 8-inch round cake pans with cooking spray.
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Line the bottoms of the pans with parchment paper, spray the paper with cooking spray and set pans aside.
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Combine the flour, cocoa powder, baking powder, baking soda, and salt together in a medium mixing bowl. (If your cocoa powder has a lot of clumps in it then sift it before mixing with the flour.) Whisk to combine, then set aside.
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Combine the sugar, butter, and vegetable oil in a large mixing bowl and whisk vigorously to combine. Whisk in the eggs and vanilla.
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Use a rubber spatula to mix the dry ingredients into the wet ingredients, then slowly mix in the coffee, stirring until just incorporated. (Take care to scrape the bottom of the bowl while you’re mixing to ensure all of the dry ingredients are incorporated.)
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Divide batter evenly between the prepared pans and bake for 26 to 32 minutes, until the cakes spring back when touched gently with your fingertip.
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Let cake layers cool in pans for 10 minutes, then run a knife around the edge of the pans and carefully remove. Transfer to a wire rack to cool completely before filling and frosting. Take care not to over-bake or the cake layers will be dry!