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Preheat the oven to 350. Spray 3 (8-inch) round cake pans with cooking spray. Line the bottoms of the pans with parchment paper, spray the paper with cooking spray and lightly dust with flour. Set pans aside.
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Whisk the flour, cocoa powder, baking powder, baking soda, and salt together in a medium mixing bowl and set aside. (These are your dry ingredients.)
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Combine the sugar, butter, and oil in a large mixing bowl and stir until combined. Mix in the eggs, peppermint, and vanilla.
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Use a rubber spatula to mix half of the dry ingredients into the wet ingredients until just combined. Stir in half of the coffee.
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Mix in the remaining dry ingredients, then the remaining coffee, stirring just until smooth.
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Divide batter evenly between the prepared pans and bake for 26 to 32 minutes, until the cakes spring back when touched gently with your finger.
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Let cake layers cool in pans for 20 minutes, then carefully remove from the pans to cool completely on a wire rack before filling and frosting your cake.