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Preheat the oven to 350 degrees. Spray 2 8-inch cake pans with cooking spray and line the bottom of the pans with parchment. Spray the parchment with more cooking spray and set pans aside.
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Whisk the dry ingredients (flour through salt) together in a medium bowl. (If your cocoa powder is lumpy, sift it first.)
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Place the butter in a large bowl and beat with an electric mixer until smooth and creamy. Add the sugar and beat on medium until very light and creamy, several minutes.
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Add the the eggs one at a time, beating well after each addition. Beat in the the yolk and vanilla to combine. Scrape down the sides and bottom of the bowl.
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With mixer on low, gradually beat in half of the dry ingredients, followed by half of the buttermilk. Beat only until combined; you don’t want to over-mix.
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Scrape down the bowl again, then beat in the remaining dry ingredients followed by the remaining buttermilk. Again beat until just combined.
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Use a rubber spatula to fold in the melted chocolate and ensure that all the flour is mixed into the cake batter.
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Divide the batter between the prepared cake pans and bake 42 to 48 minutes, until a cake tester inserted into the center of the cake layers comes out clean.
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Cool cake in the pans for 20 minutes, then run a knife around the outside of each layer to loosen. Carefully invert the cake layers onto a wire rack to cool completely before frosting.